Rubidium penta­aqua­(l-serine)cobalt(II) hexa­hydrogenhexa­molybdocobaltate(III) l-serine monosolvate deca­hydrate

摘要

The Co²⁺ ion in the title compound, Rb[Co(C3H7NO3)(H2O)5][H6CoMo6O24]·C3H7NO3·10H2O, is coordinated by five water mol­ecules and one O-monodentate l-serine ligand in a slightly distorted octahedral geometry. The Rb⁺ ion is irregularly coordinated by nine O atoms. In the crystal, the [H6Co^IIIMo6O24]³⁻ polyanions are stacked along the b-axis direction, mediated by bridging Rb—O bonds. N—H⋯O and O—H⋯O hydrogen bonds are observed involving the l-serine mol­ecules.