Crystal structure and Hirshfeld surface analysis of di­iodido­{N′-(E)-(phen­yl)(pyridin-2-yl-κN)methylidenepyridine-2-carbohydrazide-κ2N′O}cadmium(II)

摘要

In each of the two independent mol­ecules in the asymmetric unit of the title compound, [CdI2(C18H14N4O)], the N,O,N′-tridentate N′-[(E)-(phen­yl)(pyridin-2-yl-κN)methyl­idene]pyridine-2-carbohydrazide ligand and two iodide anions form an I2N2O penta­coordination sphere, with a distorted square-pyramidal geometry, with an I atom in the apical position. Both mol­ecules feature an intra­molecular N—H⋯N hydrogen bond. In the crystal, weak aromatic π–π stacking inter­actions [centroid–centroid separation = 3.830 (2) Å] link the mol­ecules into dimers.