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Characterization of Odors of Wood by Gas Chromatography-Olfactometry with Removal of Extractives as Attempt to Control Indoor Air Quality

机译:尝试通过去除萃取物来控制室内空气质量的气相色谱-比色法表征木材的气味

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摘要

Indoor air quality problems are usually revealed by occupants’ complaints. In this study, the odors of two types of hardwood species, namely, Cathy poplar (Populus cathayana Rehd.) and rubberwood (Hevea brasiliensis) were selected and extracted with ethanol-toluene for removal of extractives in an attempt to eliminate the odors. The odorous components of neat and extracted woods were identified by gas chromatography-mass spectrometry/olfactometry (GC-MS/O). The results showed that about 33 kinds of key volatile compounds (peak area above 0.2%) were detected from the GC-MS, and about 40 kinds of odorants were identified from GC-O. The components were concentrated between 15 and 33 min in GC-O, which was different from the concentration time in GC-MS. Lots of the odors identified from GC-O were unpleasant to humans, and variously described as stinky, burnt, leather, bug, herb, etc. These odors may originate from the thermos-oxidation of wood components. After extraction, the amounts and intensities of some odorants decreased, while some remained. However, the extraction process resulted in a benzene residue and led to increased benzene odor.
机译:室内空气质量问题通常通过乘员的抱怨来揭示。在这项研究中,选择了两种硬木树种的气味,即Cathy杨树(Populus cathayana Rehd。)和橡胶木(Hevea brasiliensis),并用乙醇-甲苯萃取以去除萃取物,以消除异味。通过气相色谱-质谱/嗅觉法(GC-MS / O)鉴定纯净木材和提取木材的气味成分。结果表明,从GC-MS中检出了约33种主要挥发性化合物(峰面积在0.2%以上),从GC-O中鉴定出了约40种臭味。组分在GC-O中浓缩15至33分钟,这与GC-MS中的浓缩时间不同。从GC-O鉴定出的许多气味对人类来说都是不愉快的,并被描述为臭味,烧伤,皮革,虫子,药草等。这些气味可能源自木材成分的热氧化。提取后,一些气味剂的数量和强度降低,而其余保留。但是,萃取过程会产生苯残留物,并导致增加苯气味。

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