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Sinapyl Alcohol Derivatives from the Lipo-soluble Part of Dichrocephala benthamii C. B. Clarke

机译：Dichrocephala benthamii C. B. Clarke脂溶性部分的Sinapyl醇衍生物

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Four new sinapyl alcohol derivatives dichrocephols A–D (compounds >1–>4) were isolated from the lipo-soluble part of the whole herb of Dichrocephala benthamii C. B. Clarke, together with the known compound syringenin isovalerate (>5). Their structures were elucidated on the basis of spectroscopic analysis. Their absolute configurations were established by the method of alkaline hydrohysis. Compounds >1–>3 showed moderate cytotoxity against HeLa cells, with IC50 values of 14.8 μM, 51.6 μM and 81.6 μM, respectively. This is the first time that sinapyl alcohol derivatives were isolated from the genus Dichrocephala.

机译：从整个地衣草中的脂溶性部分中分离出四种新的芥子醇衍生物双色酚A–D（化合物> 1 – > 4 ）以及已知的复方新戊二烯异戊酸酯（> 5 ）。在光谱分析的基础上阐明了它们的结构。通过碱性水解的方法确定了它们的绝对构型。化合物> 1 – > 3 对HeLa细胞具有中等细胞毒性，IC50值分别为14.8μM，51.6μM和81.6μM。这是首次从Dichrocephala属中分离出芥子醇衍生物。

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期刊名称 Molecules
作者
Xinhui Tian; Gang Ding; Chaozhong Peng; Yanbao Hu; Li Li; Hong Chen; Zhongmei Zou;
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作者单位

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年(卷),期 2013(18),2
年度 2013
页码 1720–1727
总页数 8
原文格式 PDF
正文语种
中图分类分子生物学;
关键词
Dichrocephala benthamii C. B. Clarke Asteraceae sinapyl alcohol derivatives absolute configuration determination cytotoxicity;

机译：Dichrocephala benthamii C. B. Clarke;菊科;芥子醇衍生物;绝对构型测定;细胞毒性;

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1. Sinapyl Alcohol Derivatives from the Lipo-soluble Part of Dichrocephala benthamii C. B. Clarke [J] . Xinhui Tian, Gang Ding, Chaozhong Peng Molecules . 2013,第2期

机译：Dichrocephala benthamii C. B. Clarke脂溶性部分的Sinapyl醇衍生物
2. Sinapyl Alcohol Derivatives from the Lipo-soluble Part of Dichrocephala benthamii C. B. Clarke [J] . Molecules . 2013,第2期

机译：Dichrocephala benthamii C. B. Clarke脂溶性部分的Sinapyl醇衍生物
3. ESSAYS IN SURGERY. Presented to Dr W.E. Gallie on the occasion of his retirement from the Chair of Surgery in the University of Toronto. With contributions by C. H. Best, A. B. Le Mesurier, H. M. Coleman, J.H. Couch, G. R. Walker, H. S. Coulthard, W.G. Carscadden, G. M. Dale, J. A. Dickson, A. W. Farmer, J. C. Boileau Grant, C. G Smith, D. R. Mitchell, S. J. Shane, W. T. Mustard, J. E. Batemnan, R. V. B. Shier, A. W. M. White, C. W. Harris, H. Wookey, F. R. Wilkinson, S. A. Thomson, R. V. B. Wansbrough, F. Turnbull, G. E. Richards, R. M. Janes, V, Peters, C. Ash, S. Gordon, A. Ham, F. G. Kergin, J. W. Ross, K. G. McKenzie, w. D. Stevenson, J. Gray, R. C. Laird, W. Boyd, G. E. Wilson, R. I. Harris, R. R. Graham, W. R. Campbell, W. L. Robinson, J. D. Mills, C. H. Watson, D. W. Pratt, J. L. McDonald, J. C. McClelland, K. H. Davis, E. Massig, E. B. Tovee, L. R. Dragstedt, W. K. Welsh, l, Macdonald, R. Pearse, R. A. McComb, N. C. Delarue, H. G. Armstrong, C. Aberhart, 9x6 in. Pp. xxiv -584, [J] . Reginald Watson-Jones The Journal of Bone and Joint Surgery. British VolumecBritish Orthopaedic Association , Australian Orthopaedic Association , Canadian Orthopaedic Association . . . [et al] . 1951,第3期

机译：手术中的散文。呈现给W.E博士。 Gallie在他从多伦多大学的手术主席退休的情况下。随着C. H. Best的贡献，A. B.Le Mesurier，H. M. Coleman，J.H。沙发，GR Walker，HS Coulthard，WG Carscadden，GM Dale，Ja Days，AW Farmer，JC Booteau Grant，C. G Smith，Mitchell，SJ Shane，WT Mustard，Je Batemnan，Rvb Shier，AWM White，CW Harris， H. Wookey，FR Wilkinson，Sa Thomson，Rvb Wansbrough，F. Turnbull，Ge Richards，RM Janes，V，Peters，C. Ash，S. Gordon，A. Ham，FG Kergin，JW Ross，KG McKenzie，W。 D. Stevenson，J. Gray，RC莱尔德，W. Boyd，Ge Wilson，Ri Harris，RR Graham，WR Campbell，WL Robinson，JD Mills，CH Watson，DW Pratt，JL McDonald，JC McClelland，Kh Davis，E。 Massig，EB ayvee，LR Dragstedt，WK Welsh，L，麦克唐纳，R. Parse，Ra McComb，NC Desarue，HG Armstrong，C. Aberhart，9x6。PP。 xxiv -584，
4. Stereochemistry on the Formation of Syringylglycerol-8-O-4'-(Sinapyl Alcohol) Ether from Sinapyl Alcohol with Enzyme Preparations of Eucommia ulmoides [C] . Shameul Alam, Takeshi Katayama, Toshisada Suzuki International Symposium on Wood Science and Technology（IAWPS 2008）(国际木材产品学会联合会2008学术研讨会) . 2008

机译：杜仲杜仲的酶法制备自Sinapyl醇形成Syringylglycerol-8-O-4'-（Sinapyl Alcohol）醚的立体化学
5. A. Studies towards the formation of asymmetric quaternary centres via radical allylation. B. Applications of chiral hydrazide organocatalysts to Diels-Alder, hydride reduction, and alpha-chlorination reactions. C. Studies directed towards the synthesis of potential HIV-1 reverse transcriptase inhibitors: 9-Alkylaryl TIBO derivatives. [D] . Aumand, Livia M. 2005

机译：A.关于通过自由基烯丙基化形成不对称四元中心的研究。 B.手性酰肼有机催化剂在Diels-Alder，氢化物还原和α-氯化反应中的应用。 C.针对潜在的HIV-1逆转录酶抑制剂的合成的研究：9-烷基芳基TIBO衍生物。
6. In Silico Study of the Resistance to Organophosphorus Pesticides Associated with Point Mutations in Acetylcholinesterase of Lepidoptera: B. mandarina B. mori C. auricilius C. suppressalis C. pomonella H. armígera P. xylostella S. frugiperda and S. litura [O] . Francisco Reyes-Espinosa, Domingo Méndez-Álvarez, Miguel A. Pérez-Rodríguez, 2019

机译：在鳞翅目昆虫的乙酰胆碱酯酶中与点突变相关的有机磷农药抗性的计算机研究中：曼氏芽孢杆菌桑氏芽孢杆菌C。auriciliusC.hibisalisC。pomonellaH。armígeraP。xylostellaS。frugiperda和荔枝
7. Sinapyl Alcohol Derivatives from the Lipo-soluble Part of Dichrocephala benthamii C. B. Clarke [O] . Xinhui Tian, Zhongmei Zou, Hong Chen, 2013

机译：来自Dichrocephala benthamii C. B. Clarke的脂溶性部分的芥子醇衍生物

Sinapyl Alcohol Derivatives from the Lipo-soluble Part of Dichrocephala benthamii C. B. Clarke

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