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Complexes With Biologically Active Ligands. Part 71 Synthesis andFungitoxic Activity of Metal Complexes Containing 135-tris-(8-Hydroxyquinolino)- Trichlorocyclo-Triphosphazatriene

机译:具有生物活性配体的复合物。第71部分合成及含135-三(8-羟基喹啉)-三氯环三磷杂三烯的金属配合物的真菌毒性

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摘要

Complexes containing 1,3,5-tris-(8-hydroxyquinolino)-trichlorocyclotriphosphazatriene, a new cyclophosphazene ligand, and Co(II), Cu(II) and Ni(II) were prepared. The new complexes, having the general formula [MLCl2], [ML2]Cl2, (M=Cu, Co, Ni); [NiLAc], [NiL2Ac]Ac and [ML3]X3 (M=Ni, Co, X=Cl, Ac) were characterised by elemental analysis, electronic-, IR spectroscopy, and electrical conductivity measurements. Some of them inhibited the growth of several fungi species (Aspergillus and Candida spp.)
机译:制备了含有1,3,5-三(8-羟基喹啉基)-三氯环三磷杂三烯,新的环磷腈配体以及Co(II),Cu(II)和Ni(II)的配合物。具有通式[MLCl 2],[ML 2] Cl 2(M = Cu,Co,Ni)的新配合物; [NiLAc],[NiL2Ac] Ac和[ML3] X3(M = Ni,Co,X = Cl,Ac)通过元素分析,电子,红外光谱和电导率测量进行表征。其中一些抑制了几种真菌的生长(曲霉和念珠菌属)。

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