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Wide-gamut lasing from a single organic chromophore

机译:单一有机发色团的宽色域激光发射

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摘要

The development of wideband lasing media has deep implications for imaging, sensing, and display technologies. We show that a single chromophore can be engineered to feature wide-gamut fluorescence and lasing throughout the entire visible spectrum and beyond. This exceptional color tuning demonstrates a chemically controlled paradigm for light emission applications with precise color management. Achieving such extensive color control requires a molecular blueprint that yields a high quantum efficiency and a high solubility in a wide variety of liquids and solids while featuring a heterocyclic structure with good steric access to the lone pair electrons. With these requirements in mind, we designed a lasing chromophore that encloses a lasing color space twice as large as the sRGB benchmark. This record degree of color tuning can in principle be adapted to the solid state by incorporating the chromophore into polymer films. By appropriately engineering the base molecular structure, the widest range of lasing wavelengths observed for a conventional gain medium can be achieved, in turn establishing a possible route toward high-efficiency light emitters and lasers with near-perfect chromaticity.
机译:宽带激光媒体的发展对成像,传感和显示技术有着深远的影响。我们表明,可以设计单个发色团,以在整个可见光谱及更远范围内具有宽色域荧光和激光发射特性。这种出色的色彩调节展示了具有精确色彩管理的化学控制范式,适用于发光应用。要实现这种广泛的色彩控制,就需要一种分子蓝图,该蓝图可在多种液体和固体中产生高量子效率和高溶解度,同时具有杂环结构,对孤对电子具有良好的空间位置。考虑到这些要求,我们设计了一种激光发色团,该发色团所包围的激光色空间是sRGB基准的两倍。通过将发色团结合到聚合物膜中,该创纪录的颜色调节程度原则上可以适合于固态。通过适当地设计基础分子结构,可以实现传统增益介质中观察到的最大激光波长范围,进而为通向高效发光体和具有接近完美色度的激光器建立了一条可能的途径。

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