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Visible Light-Responsive Photocatalytic Activity of Boron Nitride Incorporated Composites

机译:氮化硼掺入复合材料的可见光响应光催化活性

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摘要

Photocatalysts are essential to promote the highly efficient applications of solar energy in water splitting and/or the degradation of organic contaminations. Especially, the visible light-responsive photocatalysts could benefit with the cost-effective splitting or degradation due to the unlimited sunlight and the absence of expensive light emitter. In the photocatalysts, the charge transfer rates as well as the hole-electron recombination rate are two critical factors that determine the photocatalytic activity, which could also be affected by the dimension, defects, doping and morphologies controlled by the synthesis methods. Boron nitride (BN) is an ultrawide-bandgap semiconductor, and the combination of BN with the visible light-responsive photocatalysts has been found to be effective in enhancing the photocatalytic activities. Therefore, it should be meaningful to understand the BN incorporated photocatalytic composites in depth, including the synthetic approaches, the activity improving mechanisms and the versatile applications. In this review, we mainly focused on the assembly method of BN incorporated photocatalysts; the activity enhancing mechanism by introducing the BN in the photocatalytic composites as well as the properties and the applications. In the end, we gave a conclusion and an outlook for the BN incorporated photocatalytic composites.
机译:光催化剂对于促进太阳能在水分解和/或有机污染物的降解中的高效应用至关重要。特别地,由于无限的日光和不存在昂贵的发光体,可见光响应性光催化剂可受益于具有成本效益的分裂或降解。在光催化剂中,电荷转移速率以及空穴-电子复合速率是决定光催化活性的两个关键因素,其也可能受合成方法控制的尺寸,缺陷,掺杂和形态的影响。氮化硼(BN)是超宽带隙半导体,并且已经发现BN与可见光响应型光催化剂的组合有效地增强了光催化活性。因此,深入了解BN掺入的光催化复合材料将是有意义的,包括合成方法,活性改善机理和用途广泛。在这篇综述中,我们主要关注掺入BN的光催化剂的组装方法。通过在光催化复合材料中引入BN来增强活性,以及​​其性能和应用。最后,我们给出了掺入BN的光催化复合材料的结论和展望。

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