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Characterization and Adsorption Behavior of Strontium from Aqueous Solutions onto Chitosan-Fuller’s Earth Beads

机译:水溶液中锶对壳聚糖-富勒土珠的表征和吸附行为

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摘要

Fuller’s earth spherical beads using chitosan as a binder were prepared for the removal of strontium ions from aqueous solution. The adsorbents were characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), which revealed the porous nature of the beads. The Brunauer–Emmett–Teller (BET) surface area of the beads was found to be 48.5 m2/g. The adsorption capacities of the beads were evaluated under both batch and dynamic conditions. The adsorption capacity was found to be ~29 mg/g of adsorbent at 298 K when the equilibrium concentration of strontium in the solution was 925 mg/L at pH 6.5. The X-ray photoelectron spectroscopy (XPS) data suggest that strontium uptake by the beads occurs mainly through an ion-exchange process. Kinetic data indicate that the sorption of strontium onto the beads follows anomalous diffusion. Thermodynamic data suggest that the ion-exchange of Sr2+ on the bead surface was feasible, spontaneous and endothermic in nature.
机译:使用脱乙酰壳多糖作为粘合剂制备了富勒的地球球形珠粒,用于从水溶液中去除锶离子。吸附剂通过扫描电子显微镜(SEM)和透射电子显微镜(TEM)进行表征,揭示了微珠的多孔性。珠子的布鲁诺-埃米特-泰勒(BET)表面积为48.5 m 2 / g。在间歇和动态条件下均评估了珠粒的吸附能力。当溶液中锶的平衡浓度在pH 6.5时为925 mg / L时,在298 K时的吸附容量为〜29 mg / g吸附剂。 X射线光电子能谱(XPS)数据表明,小珠对锶的吸收主要通过离子交换过程发生。动力学数据表明,锶在微珠上的吸附遵循异常扩散。热力学数据表明,Sr 2 + 在磁珠表面的离子交换是可行的,自然的,自吸的。

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