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Effect of Polymer Blends on the Properties of Foamed Wood-Polymer Composites

机译:聚合物共混物对发泡木塑复合材料性能的影响

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摘要

The polypropylene (PP)/wood flour (WF) composites were prepared using a co-rotating twin-screw extruder followed by a single-screw extruder foaming system in this paper. Polymers, such as polyolefin elastomer (POE), high-density polyethylene (HDPE) or microcrystalline wax, were blended with PP in the preparation of composites to improve the melt strength. And a cavity transfer mixer was introduced to increase the distribution uniformity of components in composites. Meanwhile, the effect of the polymer blends on the microstructure and mechanical properties of samples was investigated. The experimental results show that the addition of POE and HDPE resulted in the second melting peak in the differential scanning calorimeter (DSC) curves and a great decrease in the cell size was caused by the added POE. However, due to the velocity difference of composites in the die, the shape of bubbles gradually became irregular. Moreover, the impact strength of samples significantly increased by 85% for the added POE and the apparent density decreased by 6.7%. And the minimum Vicat softening temperature of 133.7 °C was obtained when the mass ratio of HDPE to PP was 4/6.
机译:聚丙烯(PP)/木粉(WF)复合材料的制备方法是使用同向双螺杆挤出机,然后采用单螺杆挤出机发泡系统。在制备复合材料时,将聚合物(例如聚烯烃弹性体(POE),高密度聚乙烯(HDPE)或微晶蜡)与PP共混以提高熔体强度。为了提高复合材料中各组分的分布均匀性,引入了腔转移混合器。同时,研究了聚合物共混物对样品微观结构和力学性能的影响。实验结果表明,POE和HDPE的加入导致了差示扫描量热仪(DSC)曲线中的第二个熔融峰,而POE的加入导致了细胞尺寸的极大减小。然而,由于模具中复合材料的速度差异,气泡的形状逐渐变得不规则。此外,添加的POE的冲击强度显着提高了85%,表观密度降低了6.7%。 HDPE与PP的质量比为4/6时,维卡软化最低温度为133.7°C。

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