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Amino Acids Aided Sintering for the Formation of Highly Porous FeAl Intermetallic Alloys

机译:氨基酸辅助烧结形成高多孔FeAl金属间化合物

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摘要

Fabrication of metallic foams by sintering metal powders mixed with thermally degradable compounds is of interest for numerous applications. Compounds releasing gaseous nitrogen, minimizing interactions between the formed gases and metallic foam by diluting other combustion products, were applied. Cysteine and phenylalanine, were used as gas releasing agents during the sintering of elemental Fe and Al powders in order to obtain metallic foams. Characterization was carried out by optical microscopy with image analysis, scanning electron microscopy with energy dispersive spectroscopy, and gas permeability tests. Porosity of the foams was up to 42 ± 3% and 46 ± 2% for sintering conducted with 5 wt % cysteine and phenylalanine, respectively. Chemical analyses of the formed foams revealed that the oxygen content was below 0.14 wt % and the carbon content was below 0.3 wt %. Therefore, no brittle phases could be formed that would spoil the mechanical stability of the FeAl intermetallic foams. The gas permeability tests revealed that only the foams formed in the presence of cysteine have enough interconnections between the pores, thanks to the improved air flow through the porous materials. The foams formed with cysteine can be applied as filters and industrial catalysts.
机译:通过烧结与可热降解的化合物混合的金属粉末来制造金属泡沫对于许多应用是令人感兴趣的。使用了释放气态氮,通过稀释其他燃烧产物来最大程度降低所形成的气体与金属泡沫之间的相互作用的化合物。半胱氨酸和苯丙氨酸在烧结元素铁粉和铝粉时用作气体释放剂,以获得金属泡沫。通过具有图像分析的光学显微镜,具有能量色散光谱的扫描电子显微镜和透气性测试进行表征。对于用5重量%的半胱氨酸和苯丙氨酸进行的烧结,泡沫的孔隙率分别高达42±3%和46±2%。所形成的泡沫的化学分析表明,氧含量低于0.14wt%,碳含量低于0.3wt%。因此,不能形成会破坏FeAl金属间泡沫的机械稳定性的脆性相。透气性测试表明,由于在多孔材料中的气流得到改善,因此只有在半胱氨酸存在下形成的泡沫在孔之间具有足够的互连性。由半胱氨酸形成的泡沫可用作过滤器和工业催化剂。

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