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Two-Way Shape Memory Effect Induced by Tensile Deformation in Columnar-Grained Cu71.7Al18.1Mn10.2 Alloy

机译:柱状晶粒Cu71.7Al18.1Mn10.2合金的拉伸变形引起的双向形状记忆效应

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摘要

Columnar-grained Cu71.7Al18.1Mn10.2 shape memory alloy (SMA) was prepared by a directional solidification method and exhibited a high superelasticity of 8.18% and excellent ductility at room temperature, which provided the possibility of obtaining high shape memory. However, proper pre-deformation is an essential part of repeatedly obtaining large and stable shape change. In this paper, one-time uniaxial tensile pre-deformation was carried out at the temperature range −70–−80 °C. Then, the two-way shape memory effect (TWSME) of the alloy was evaluated by the martensitic transformation strain (εM) which was measured by a thermal expansion test to investigate the relationship between the pre-deformation strain (εT) and the TWSME. The results showed that εM of the columnar-grained Cu71.7Al18.1Mn10.2 alloy increased at first and then decreased with the increase of εT. The maximum value 2.91% of the εM could be reached when εT was 6%. The effects of the εT on transformation temperatures were also measured by differential scanning calorimetry. Based on the variations of transformation temperatures, the relationship between the internal stress induced by the pre-deformation process and the εM, and the influence mechanism of the pre-deformation strain on the TWSME in columnar-grained Cu71.7Al18.1Mn10.2 alloy, were discussed. The results obtained from this work may provide reference for potential applications of Cu-based SMAs, such as self-control components, fasteners, etc.
机译:通过定向凝固法制备了圆柱状的Cu71.7Al18.1Mn10.2形状记忆合金(SMA),具有8.18%的高超弹性和室温下的优良延展性,为获得高形状记忆提供了可能。但是,适当的预变形是反复获得大而稳定的形状变化的必要部分。在本文中,在-70–-80°C的温度范围内进行了一次单轴拉伸预变形。然后,通过马氏体转变应变(εM)评估合金的双向形状记忆效应(TWSME),该应变通过热膨胀测试测量以研究变形前应变(εT)与TWSME之间的关系。结果表明,柱状晶粒Cu71.7Al18.1Mn10.2合金的εM先增大,然后随着εT的增加而减小。当εT为6%时,可达到εM的最大值2.91%。还通过差示扫描量热法测量了εT对转变温度的影响。根据相变温度的变化,预测了柱状晶粒Cu71.7Al18.1Mn 中预变形过程引起的内应力与εM之间的关系,以及预变形应变对TWSME的影响机理。讨论了10.2 合金。这项工作获得的结果可为铜基SMA的潜在应用提供参考,例如自控组件,紧固件等。

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