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Mechanical Thermomechanical and Reprocessing Behavior of Green Composites from Biodegradable Polymer and Wood Flour

机译:来自可生物降解的聚合物和木粉的绿色复合材料的机械热机械和后处理行为

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摘要

The rising concerns in terms of environmental protection and the search for more versatile polymer-based materials have led to an increasing interest in the use of polymer composites filled with natural organic fillers (biodegradable and/or coming from renewable resources) as a replacement for traditional mineral inorganic fillers. At the same time, the recycling of polymers is still of fundamental importance in order to optimize the utilization of available resources, reducing the environmental impact related to the life cycle of polymer-based items. Green composites from biopolymer matrix and wood flour were prepared and the investigation focused on several issues, such as the effect of reprocessing on the matrix properties, wood flour loading effects on virgin and reprocessed biopolymer, and wood flour effects on material reprocessability. Tensile, Dynamic-mechanical thermal (DMTA), differential scanning calorimetry (DSC) and creep tests were performed, pointing out that wood flour leads to an improvement of rigidity and creep resistance in comparison to the pristine polymer, without compromising other properties such as the tensile strength. The biopolymer also showed a good resistance to multiple reprocessing; the latter even allowed for improving some properties of the obtained green composites.
机译:在环境保护方面日益关注的问题以及对更加通用的基于聚合物的材料的寻求,导致人们对使用填充了天然有机填料(可生物降解和/或来自可再生资源)的聚合物复合材料的兴趣日益增长。矿物无机填料。同时,聚合物的循环利用对于优化可用资源的利用,减少与聚合物基产品生命周期有关的环境影响仍然至关重要。制备了由生物聚合物基体和木粉制成的绿色复合材料,研究集中在几个问题上,例如再加工对基体性能的影响,木粉负载量对原始和再加工生物聚合物的影响以及木粉对材料可再加工性的影响。进行了拉伸,动态机械热(DMTA),差示扫描量热法(DSC)和蠕变测试,指出与原始聚合物相比,木粉可提高刚性和抗蠕变性,而不会损害其他性能,例如抗拉强度。该生物聚合物还表现出对多次再加工的良好抵抗力。后者甚至可以改善所得绿色复合材料的某些性能。

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