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Bisphenol S Adsorption Behavior on Ferralsol and Biochar Modified Soil with Dissolved Organic Matter

机译:双酚S在溶解有机质的铁酸盐和生物炭改性土壤上的吸附行为。

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摘要

Bisphenol S (BPs) has been found in a variety of common consumer products surrounding human living, despite the fact that it could damage the human digestive system and genital system. In China, straw-returning to the field is a common soil improvement technology used to increase the concentration of dissolved organic matter (DOM), which plays an important role in the natural environment as a microreactor of contaminants. Additionally, the biochar obtained by the straw is an effective soil conditioner. DOM is a key influencing factor when biochar is employed as the conditioner of BPs contaminated soil. However, the BPs adsorption behavior on the Ferralsol affected by DOM and biochar is also unclear. Hence, DOM was prepared and the effect of DOM on the BPs adsorption behavior on soil and biochar modified soil was investigated. DOM was characterized by Elemental analysis, Fourier transforming infrared spectra (FT-IR), and three-dimensional excitation-emission matrix spectra (3D-EEM). The results of the adsorption experiments indicated that both biochar and DOM could improve the BPs adsorption capacity in Ferralsol, while DOM suppressed the BPs adsorption capacity of biochar modified soil, indicating that DOM and BPs could not be applied at the same time for BPs adsorption.
机译:尽管双酚S(BPs)可能会破坏人体的消化系统和生殖器系统,但在人们周围的各种普通消费品中都发现了双酚S。在中国,将秸秆还田是提高土壤中可溶性有机物(DOM)浓度的常见土壤改良技术,它在自然环境中作为污染物的微反应器发挥着重要作用。另外,通过稻草获得的生物炭是一种有效的土壤改良剂。当生物炭用作BPs污染土壤的调节剂时,DOM是关键的影响因素。然而,BPs在受DOM和生物炭影响的Ferralsol上的吸附行为也不清楚。因此,制备了DOM,并研究了DOM对BPs在土壤和生物炭改性土壤上的吸附行为的影响。通过元素分析,傅立叶变换红外光谱(FT-IR)和三维激发发射矩阵光谱(3D-EEM)来表征DOM。吸附实验结果表明,生物炭和DOM均可提高对Ferralsol的BPs吸附能力,而DOM抑制了生物炭改性土壤的BPs吸附能力,表明DOM和BPs不能同时用于BPs吸附。

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