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Released Volatile Organic Compounds in Southern Yellow Pine before and after Heat Treatment

机译:热处理前后在南黄松中释放的挥发性有机化合物

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摘要

As the main material in indoor furniture, southern yellow pine (Pinus spp.) releases volatile organic compounds (VOCs) into the environment during use. To better understand variations in the contents of VOCs in southern yellow pine before and after heat treatment, this study conducts dry heat treatment on southern yellow pine at 140 °C and 220 °C. Headspace solid phase micro-extraction was used to extract VOCs from southern yellow pine. The VOCs of southern yellow pine before and after heat treatment were identified via gas chromatography-mass spectrometry, and chemical component differences were characterized via Fourier transform infrared spectroscopy. Results reveal 86 VOCs in pure southern yellow pine, including alcohols, aromatics, acids, aldehydes, alkanes, alkenes, and some trace compounds (e.g., furans, ketones, phenols, and esters). With an increase in heat-treatment temperature, the contents of alkanes increased, whereas those of alcohols and alkenes decreased. The contents of aromatics, acids, and aldehydes were highest when heat treated at 140 °C. At 220 °C, the total contents of key VOCs in southern yellow pine were lowest.
机译:作为室内家具的主要材料,南方黄松(Pinus spp。)在使用过程中会向环境中释放挥发性有机化合物(VOC)。为了更好地了解热处理之前和之后南部黄松中VOC含量的变化,本研究在140°C和220°C下对南部黄松进行了干热处理。顶空固相微萃取用于从南部黄松中提取VOC。通过气相色谱-质谱法鉴定了热处理前后的南黄松的挥发性有机化合物,并通过傅里叶变换红外光谱法表征了化学成分的差异。结果显示纯南黄松中有86种VOC,包括酒精,芳烃,酸,醛,烷烃,烯烃和一些痕量化合物(例如呋喃,酮,酚和酯)。随着热处理温度的升高,烷烃的含量增加,而醇和烯烃的含量降低。在140°C热处理时,芳烃,酸和醛的含量最高。在220°C时,南部黄松中的主要VOC含量最低。

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