Poly[[diaquadi-μ-dicyanamido-nickel(II)] bis­(pyridinium-4-olate)]

摘要

The title compound, {[Ni(C2N3)2(H2O)2]·2C5H5NO}n, is a centrosymmetric two-dimensional coordination polymer with a layer (4,4) network structure. The asymmetric unit is compossed of an Ni^II atom, which sits on an inversion center, a μ-1,5-bridging dicyanamide anion, a water mol­ecule, and a free 4-hydroxy­pyridine mol­ecule present in the zwitterionic pyridinium-4-olate form. The Ni^II atom is coordinated in a slightly distorted N4O2 octa­hedral geometry by four bridging dicyanamide ligands and two trans water mol­ecules. In the crystal, the two-dimensional networks are linked via N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional network.