Bis[μ-1,2-diphenyl-N,N′-bis­(di-2-pyridyl­methyl­eneamino)ethane-1,2-diimine]disilver(I) bis­(hexa­fluorido­phosphate) acetonitrile disolvate

摘要

In the centrosymmetric dinuclear title compound, [Ag2(C36H26N8)2](PF6)2·2C2H3N, the Ag⁺ ion is bound to four N atoms from two 1,2-diphenyl-N,N′-bis­(di-2-pyridyl­methyl­eneamino)ethane-1,2-diimine ligands in a distorted tetra­hedral geometry. The ligand adopts a twist conformation, coordinating two metal centers by three pyridyl N atoms and one imine N atom and spanning two Ag⁺ ions, resulting in the formation of a helical dimeric structure.