Crystal structure of (3S*4S*4aS*5R*6R*6aS*7R*11aS*11bR*)-56-bis(benzo­yloxy)-34a-dihy­droxy-4711b-trimethyl-12344a566a71111a11b-dodeca­hydro­phenanthro32-bfuran-4-carb­oxy­lic acid methanol monosolvate

摘要

The title compound, C34H36O9·CH3OH, is a diterpenoid isolated from the roots of Caesalpinia pulcherrima (L.) Swartz. The three trans-fused six-membered rings are in chair, chair and half-chair conformations. The mean plane of this fused-ring system makes dihedral angles of 67.95 (15) and 83.72 (14)° with the two phenyl rings of the benzo­yloxy groups. An intra­molecular C—H⋯O hydrogen bond is observed. In the crystal, mol­ecules are linked via O—H⋯O hydrogen bonds, forming an infinite chain along the b-axis direction.