X-rayAbsorption Study of Graphene Oxide andTransition Metal Oxide Nanocomposites

摘要

The surface properties of the electrode materials play a crucial role in determining the performance and efficiency of energy storage devices. Graphene oxide and nanostructures of 3d transition metal oxides were synthesized for construction of electrodes in supercapacitors, and the electronic structure and oxidation states were probed using near-edge X-ray absorption fine structure. Understanding the chemistry of graphene oxide would provide valuable insight into its reactivity and properties as the graphene oxide transformation to reduced-graphene oxide is a key step in the synthesis of the electrode materials. Polarized behavior of the synchrotron X-rays and the angular dependency of the near-edge X-ray absorption fine structures (NEXAFS) have been utilized to study the orientation of the σ and π bonds of the graphene oxide and graphene oxide–metal oxide nanocomposites. The core-level transitions of individual metal oxides and that of the graphene oxide nanocomposite showed that the interaction of graphene oxide with the metal oxide nanostructures has not altered the electronic structureof either of them. As the restoration of the π network is importantfor good electrical conductivity, the C K edge NEXAFS spectra of reducedgraphene oxide nanocomposites confirms the same through increasedintensity of the sp²-derived unoccupied states π*band. A pronounced angular dependency of the reduced sample and theformation of excitonic peaks confirmed the formation of extended conjugatednetwork.