Here, we formulate low surface tension (∼30 mN/m) and low boiling point (∼79 °C) inks of graphene, single-wall carbon nanotubes and conductive polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) and demonstrate their viability for spray-coating of morphologically uniform (Sq ≈ 48 ± 3 nm), transparent conducting films (TCFs) at room temperature (∼20 °C), which conform to three dimensional curved surfaces. Large area (∼750 cm2) hybrid PEDOT:PSS/graphene films achieved an optical transmission of 67% in the UV and 64% in the near-infrared wavelengths with a conductivity of ∼104 S/m. Finally, we demonstrate the spray-coating of TCFs as an electrode on the inside of a poly(methyl methacrylate) sphere, enabling a semitransparent (around 360°) and spherical touch sensor for interactive devices.
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机译:在这里,我们配制了石墨烯,单壁碳纳米管和导电聚合物聚(3,4-乙撑二氧噻吩):聚(苯乙烯磺酸盐)的低表面张力(〜30 mN / m)和低沸点(〜79°C)油墨( PEDOT:PSS)并证明了其在室温(〜20°C)下喷涂形态均匀(Sq≈48±3 nm),透明导电膜(TCFs)的可行性,该膜符合三维曲面。大面积(约750 cm 2 sup>)混合PEDOT:PSS /石墨烯薄膜在紫外线下的光学透射率为67%,在近红外波长下的光学透射率为64%,电导率约为10 4 sup> S / m。最后,我们演示了将TCF喷涂为聚甲基丙烯酸甲酯球体内部的电极,从而为交互式设备提供半透明(约360°)和球形触摸传感器。
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