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EELS study on BST thin film under electron beam irradiation

     

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[11]Yoshiya, M., Tanaka, I., Kaneko, K. et al., First principles calculation of chemical shifts in ELNES/NEXAFS of titanium oxides, J. Phys.: Condens. Matter., 1999, 11: 3217 -3228.[12]Egerton, R. F., Electron Energy-Loss Spectroscopy in the Electron Microscope, New York: Plenum Press,www.scichina.com1996, 245-300.[13]Smyth, D. M., Harmer, M. P., Peng, P., Defect chemistry of relaxor ferroelectrics and the implications for dielectric degradation, J. Am. Ceram. Soc., 1989, 72 (12): 2276-2278.[14]Chan, N. H., Sharma, R. K., Smyth, D. M., Nonstoichiometry in undoped BaTiO3, J. Am. Ceram. Soc., 1981,64 (9): 556-562.[15]Leapman, R. D., Grunes, L. A., Fejes, P. L., Study of the L23 edges in the 3d transition metals and their oxides by electron-energy-loss spectroscopy with comparisons to theory, Phys. Rev. B, 1982, 26: 614-435.[16]Otten, M. T., Buseck, P. R., The oxidation state of Ti in hornblende and biotite determined by electron energy-loss spectroscopy, with inferences regarding the Ti substitution, Phys. Chem. Miner., 1987, 14:45 -51.[17]Sankararaman, M., Perry, D., Valence determination of titanium and iron using electron energy loss spectroscopy, J. Mater. Sci., 1992, 27: 2731-2733.[18]Lusvardi, V. S., Barteau, M. A., Chen, J. G. et al., An NEXAFS investigation of the reduction and reoxidation of TiO2 (001), Surf. Sci., 1998, 397: 237-250.[1]Kingon, A. I., Streiffer, S. K., Basceri, C. et al., High-permittivity perovskite thin films for dynamic random-access memories, MRS Bull., 1996, 21: 46-52.[2]Kingon, A. I., Maria, J. P., Streiffer, S. K., Alternative dielectrics to silicon dioxide for memory and logic devices, Nature (London), 2000, 406: 1032-1038.[3]Stemmer, S., Hoche, T., Keding, R. et al., Oxidation states of titanium in bulk barium titanates and in (100) fiber-textured (BaxSr1- x)Ti1+ yO3+ z thin films, Appl. Phys. Lett., 2001, 79:3149-3151.[4]Stemmer, S., Streiffer, S. K., Browning, N. D. et al., Grain boundaries in barium strontium titanate thin films: structure, chemistry and influence on electronic properties, Interface Sci., 2000, 8: 209-221.[5]Stemmer, S., Streiffer, S. K., Browning, N. D. et al., Accommodation of nonstoichiometry in (100) fibertextured (BaxSr1 -x)Ti1+ yO3+ z thin films grown by chemical vapor deposition, Appl. Phys. Lett., 1999, 74:2432-2434.[6]Jia, C. L., Lentzen, M., Urban, K., Atomic-resolution imaging of oxygen in perovskite ceramics, Science,2003, 299: 870-873.[7]Jin, H. Z., Zhu, J., Ehrhart, P. et al., An interfacial defect layer observed at (Ba, Sr)TiO3/Pt interface, Thin Solid Films, 2003, 429 (1-2): 282-285.[8]Jin, H. Z., Zhu, J., Size effect and fatigue mechanism in ferroelectric thin films, J. Appl. Phys., 2002, 92(8):4594-4598.[9]Kim, M., Ddscher, G., Browning, N. D. et al., Nonstoichiometry and the electrical activity of grain boundaries in SrTiO3, Phys. Rev. Lett., 2001, 86: 4056-4059.[10]Tafto, J., Zhu, J., Electron energy loss near edge structure (ELNES), a potential technique in the studies of local atomic arrangements, Ultramicroscopy, 1982, 9: 349-354.

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    《中国科学》|2004年第6期|P.659-666|共8页
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  • 入库时间 2023-07-24 18:24:29

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