Fluorescence and preparation of Sr_2(P_2O_7 ):Ce,Tb phosphate by co-precipitation method

摘要

The micron-sized Sr 2(P2O7):Ce,Tb green phosphors were prepared by being annealed at different temperatures with its precursors synthesized by co-precipitates of(NH4) 2HPO4 at ambient temperature. The phase structure, grain size, surface morphology, and luminescent properties of phosphors were investigated by X-ray diffraction, scanning electron microscope, transmission electron microscope, and fluorescence spectrum. The results show that the product of precursor annealed at 1,100 °C is Sr 2(P 2O7):Ce,Tb, which belongs to orthorhombic phase. The powder is spherical and the size distribution is in micron grade. The sample with the molar ratio of Sr/Tb/Ce of 100.0:0.4:0.6 shows the best fluorescence effect annealed at 1,100 °C for 3 h. The phosphors produce green fluorescence by being excitated with ultraviolet radiation of 254 nm wavelength, and the main emission peak is at 547 nm. The Sr 2(P2O7):Ce,Tb phosphors synthesized by co-precipitation method of precursors at ambient temperature is a kind of efficient green-emitting phosphors.