Two kinds of poly(vinyl alcohol)(PVA)-silica composites were prepared with different methods. One composite was prepared by directly mixing PVA with 80 nm silica nano-particles which were made from tetraethoxysilane(TEOS). The another was obtained by the mixing PVA and hydrolyzed TEOS in the presence of acid-catalyst. The properties of the two PVA/silica hybrids were characterized by means of scanning electron microscopy(SEM), UV-Visible spectroscopy,solubility tests, limiting oxygen index(LOI) test, tensile test and dynamical mechanical analysis(DMA), respectively. The results indicate that PVA-TEOS composites(PT for short) display more transparency than PVA-silica nano-particles hybrids(PS for short). At the same time, The PT composites presented more excellent performance than PS in water resistance, fire resistance and mechanical properties. Moreover, the Tg of PT increased with increasing TEOS content, while that of PS decreased.
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