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Study on Water—Soluble Organic Reducing Substances.I.Determination of Organic Reducing Substances by Differential Pulse Voltammetry

机译:水溶性有机还原性物质的研究I.差示脉冲伏安法测定有机还原性物质

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A new method was proposed for study of organic reducing substances in soils.According to the theoretical relationship between the voltammetric behaviors and reduction-oxidation reaction of reducing substances,the working conditions of differential pulse voltammetry (d.p.v.)for determining the organic reducing substances produced during the processes of the anaerobic decomposition of plant materials were established with a glass carbon electrode as working electrode,1M Ag-AgCl electrode with large area as reference electrode,0.2M NH4Ac as supporting from -0.5 to +1.2 voltage(vs.M Ag-AgCl).The peak current proportional to the concentration of reducing substances,and the characteristic peak potential of each organic reducing substance were regarded as the quantitative and qualitative base,respectively.These results obtained under the conditions mentioned above directly reflect both the reducing intensity and capacity of the organic reducing system in soils.
机译:提出了一种研究土壤中有机还原物质的新方法。根据伏安行为与还原物质还原-氧化反应的理论关系,利用差示脉冲伏安法(dpv)的工作条件确定了土壤中有机还原物质的含量。以玻璃碳电极为工作电极,1M大面积Ag-AgCl电极为参比电极,0.2M NH4Ac为-0.5至+1.2电压(vs.M Ag-),建立植物材料的厌氧分解过程。与还原物质浓度成正比的峰值电流和每种有机还原物质的特征峰电位分别被视为定量和定性的基础。在上述条件下获得的这些结果直接反映了还原强度和土壤中有机还原系统的容量。

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