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Interactions of Cations with Electrodialyzed Clay Fraction of Soils as Inferred from Wien Effect in Soil Suspensions

         

摘要

The electrical conductivities (ECs) of suspensions containing 25 and 30 g kg-1 solids prepared from theelectrodialyzed clay fraction (< 2 μm in diameter) of latosol, yellow-brown soil, and black soil, dispersed invarious nitrate solutions having concentrations of 1 × 10-4/z mol L-1, where z is the valence, and in distilledwater, were measured at field strengths ranging from 14 kV cm-1 to 210 kV cm-1. On the basis of analysesof the charge density and exchangeable ion composition on the surfaces of soil particles in the suspensions,and of the characters of the EC-field strength curves of the various suspensions, it was inferred that theincrement of EC (△EC) and/or relative electrical conductivity (REC) can indicate the bonding strengthbetween cations and soil particles. The bonding strengths of various cations with the soils diminished in theorder: K+ > Zn2+ > Mg2+ = Ca2+ > Na+ for latosol, Ca2+ > Zn2+ > Mg2+ = K+ > Na+ for yellow-brownsoil, and Zn2+ >Ca2+ > Mg2+ > K+ > Na+ for black soil.

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