Using silica as template, mesoporous cobalt silicate hollow spheres were synthesized by sacrificial template reaction.Their structures and morphologies were characterized by scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD) and temperature procedure reduction (TPR).Their reduction law was groped and catalytic performance of Co/SiO2 on nitrobenzene hydrogenation was studied.The results indicate that the structures of cobalt silicate are hollow spheres under 1 h at 180℃.Co/SiO2 hollow spheres are obtained after reduction of cobalt silicate hollow spheres within 5 h under 800℃ with less specific surface area and bigger pore size than before reduction.But the hollow spheres before and after reduction still possess the similar hollow spheres.Using Co/SiO2 hollow spheres used as catalyst on conversion of nitrobenzene, the conversion rate reaches 56% within 1 h, about 14% higher than that of using commercial Raney Ni.%以二氧化硅为模板,采用牺牲模板法制备具有介孔结构的碱式硅酸钴空心球.采用扫描电子显微镜(SEM),透射电子显微镜(TEM)、X射线衍射(XRD)、氮气吸脱附曲线(BET)和程序升温还原(TPR)等方法,对样品的结构和形貌作了表征.探索了碱式硅酸钴空心球的还原规律,研究了Co/SiO2作催化剂的催化性能.结果表明,180℃下反应1 h时,碱式硅酸钴即为空心球结构;在800℃氢气气氛中反应5 h,碱式硅酸钴完全被还原为Co/SiO2,还原前后仍为空心球结构,比表面积和孔容均有所减小,孔径增大.以Co/SiO2空心球做催化剂进行硝基苯加氢催化,1 h后硝基苯的转化率为56%,比商用Raney Ni提高约14%.
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