Y2O3 (5mol%) and Gd2O3 (5mol%) co-doped SiZrO3 (Sr(Zr0.9Y0.05Gd0.05)O2.95, SZYG) was synthesized by solid state reaction method. The phase stability of the SZYG powder synthesized at high temperature of 1450°C for a long period and at temperature range of 200-1400°C was characterized by XRD and DSC, respectively. The coefficients of thermal expansion (CTEs) of bulk SZYG recorded by a high-temperature dilatometer show that the phase transitions of SrZrO3 is suppressed remarkably by co-doping Y2O3 and Gd2O3. The thermal conductivity of bulk SZYG at 10001 is 1.36 W/(mK), which is 35% lower than that of bulk SrZrO3 and 8YSZ. The good chemical compatibility of SZYG with 8YSZ and A12O3, is detected after heat-treatment at 1250°C for 24 h.%采用固相反应法合成了5mol% Y2O3与5mol% Gd2O3共掺杂SrZrO3(Sr(Zr0.9Y0.05Gd0.05)O2.95,SZYG)粉末.采用X射线衍射(XRD)和差示扫描量热仪(DSC)分别研究了SZYG粉末在1450℃长期热处理后以及200~1400℃范围内的相稳定性.采用高温热膨胀仪测量了SZYG块材的热膨胀系数,结果表明:通过Y2O3与Gd2O3共掺杂改性可以明显抑制SrZrO3的相转变.在1000℃下SZYG块材的热导率是~1.36 W/(m.K),与SrZrO3和8YSZ块材相比降低~35% SZYG分别与8YSZ和Al2O3在1250℃热处理24h表现出很好的化学相容性.
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