光致氧化还原调控的活性聚合

摘要

In recent years,the controlled radical polymerization through photoredox catalysis has been developed rapidly.The extension of the suitable monomer range and the optimization of reaction conditions make this method a useful way to synthesize functional polymer materials.In this review,the recent progress in photoredox controlled living polymerization was summarized,and some representative examples involving the use of monomer types were discussed.We hope this review can provide researchers with new ways and ideas for designing novel photopolymerization and functional polymer materials.%近几年,光致氧化还原调控的可控自由基聚合得到了迅速发展,其适用单体范围广、反应条件温和,为合成聚合物和功能高分子材料提供了新方法.本综述对光致氧化还原调控活性聚合进行了总结与探讨,归纳整理了多种单体聚合的最新研究进展,为研究人员探索光催化聚合反应、设计合成功能高分子材料提供了新思路.