Compilation of reaction kinetics parameters determined in the Key Development Project for Air Pollution Formation Mechanism and Control Technologies in China

摘要

A compilation of new advances made in the research?eld of laboratory reaction kinetics in China’s Key Development Project for Air Pollution Formation Mechanism and Control Technologies was presented.These advances are grouped into six broad,interrelated categories,including volatile organic compound(VOC)oxidation,secondary organic aerosol(SOA)formation,new particle formation(NPF)and gas-particle partitioning,ozone chemistry,model parameters,and secondary inorganic aerosol(SIA)formation,highlighting the laboratory work done by Chinese researchers.For smog chamber applications,the current knowledge gained from laboratory studies is reviewed,with emphasis on summarizing the oxidation mechanisms of long-chain alkanes,aromatics,alkenes,aldehydes/ketones in the atmosphere,SOA formation from anthropogenic emission sources,and oxidation of aromatics,isoprene,and limonene,as well as SIA formation.For?ow tube applications,atmospheric oxidation mechanisms of toluene and methacrolein,SOA formation from limonene oxidation by ozone,gas-particle partitioning of peroxides,and sulfuric acid-water(H2SO4-H2O)binary nucleation,methanesulfonic acid-water(MSA-H2O)binary nucleation,and sulfuric acid-ammonia-water(H2SO4-NH3-H2O)ternary nucleation are discussed.