首页> 中文期刊> 《高校化学工程学报》 >间苯二甲腈在四种溶剂中溶解度的测定及关联

间苯二甲腈在四种溶剂中溶解度的测定及关联

         

摘要

采用平衡法分别测定了间苯二甲腈在甲醇、甲苯、二甲苯和苯胺四种溶剂中的溶解度,温度范围为293.15~318.15 K,并分别采用λ-h方程、Apelblat模型和Yaws模型对实验数据进行了关联.根据实验数据可以看出间苯二甲腈的溶解度在4种溶剂中均随着温度的升高而升高,并且间苯二甲腈在不同溶剂中的溶解度差别较大.通过4个体系的24个数据点的实验值与计算值相比较,三种模型的总的平均相对误差分别为5.92%、3.90%、3.86%.结果表明λ-h方程、Apelblat模型和Yaws模型都可以较好地关联间苯二甲腈在四种溶剂中的溶解度数据.%The solubility data of isophthalonitrile (IPN) in methanol, toluene, dimethylbenzene and aniline at 293.15~381.15 K were determined by equilibrium method. The experimental data were correlated with λ-h equation, Apelblat equation and Yaws equation, respectively. According to the experimental data, the solubilities of IPN in above mentioned 4 solvent systems increase with increasing temperature, and they are of great difference in different solvents. Comparing 24 data of IPN solubility in above 4 solvent systems, the average absolute deviations between the experimental values of IPN solubility and those calculated by above three equations are 5.92%, 3.90% and 3.86%, respectively. The results show that all the λ-h equation, Apelblat equation and Yaws equation could well correlate the solubility data of IPN in those 4 mentioned solvents.

著录项

相似文献

  • 中文文献
  • 外文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号