This paper gave a theory based on rate equation. From this theory, we can get the rotate population and its evolvement of hydroxyl radical from laser acting with O3 and H2O in measuring hydroxyl radical used LIF. The interfere intensity from nascent hydroxyl radical is also been discussed.%对激光诱导荧光法测量对流层OH自由基时,激光与大气中的臭氧及水蒸气作用产生的OH自由基的转动态分布及其随时间的演化进行了研究,并对新生的OH自由基对荧光信号的干扰强度进行了讨论。
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