Up-grading of natural ilmenite ore by combining oxidation and acid leaching

摘要

Rutile(TiO_2) is heavily used in pigments and colorants, and the most abundant source of rutile is ilmenite. Upon oxidation of ilmenite, rutile can be formed with modest energy consumption; furthermore, after leaching, only a few byproducts are formed. Unfortunately, one drawback is the necessarily long oxidative process of typically used methods. In this study, we show that a fluidized bed reactor can be used to oxidize ilmenite ore to rapidly form rutile and pseudobrookite(Fe_2TiO_5) phases. Ilmenite was oxidized with 5 vol% O_2 in Ar at temperatures of 1173 K or 1223 K and subsequently leached using a diluted H_2SO_4 solution to dissolve the pseudobrookite phase. The effects of acid concentration, temperature, and cooling rate after oxidation were investigated. We show that the ilmenite was rapidly oxidized to form rutile and pseudobrookite phases at 1173 and 1223 K in a 5 vol% O_2/95 vol% Ar environment within 40 min. The final maximum rutile yield was 84.2 mol% after leaching in(1 + 1) H_2SO_4 solution at 393 K for 12 h.