官能团化烯烃的氢甲酰化反应研究及应用进展

摘要

氢甲酰化反应已发展成为重要的工业均相催化反应之一，通过官能团化烯烃氢甲酰化反应可以得到官能团化的醛类化合物，该类化合物大多是精细化学品或合成中间体，官能团化烯烃显示出很多不一样的特性。综述近年来官能团化烯烃氢甲酰化反应研究进展，介绍乙烯基芳烃、α-官能团化烯烃以及β-官能团化烯烃的氢甲酰化反应及应用，并对官能团化烯烃氢甲酰化反应进行展望。%Hydroformylation is one of the most important homogeneous catalytic processes in industry. Hydroformylation of functionalized olefins provides the routes to obtaining aldehydes with one or more additional functional groups. Such functionalized aldehydes can be sold as final products or used as inter-mediates in the synthesis of fine chemicals,pharmaceuticals and fragrances. The hydroformylation showed distinct differences compared to the reaction with unfunctionalized alkenes. In this paper,the progress in hydroformylation of functionalized olefins and its application were introduced,including vinyl arenes,α-functionalized olefins and β-functionalized olefins. The development prospects of hydroformylation of functionalized olefins was put forward.