Hierarchical Co_(3)O_(4)@NiCoLDH nanosheets(NSs)were prepared on carbon cloth through a multistep method,containing Metal-organic frameworks(MOF)-templated thermal annealing and electrodeposition.The triangle-shaped Co_(3)O_(4 NSs)were firstly obtained by thermal treatment of MOF templates in air.Then,ultrathin NiCoLDH_(NSs)were in-situ electrodeposited on the surface of Co_(3)O_(4NSs),constructing a core-shell structure.Benefiting the unique hierarchical structure,high conductivity of Co_(3)O_(4 NSs)core and large surface area of NiCoLDHNSs shell,the Co_(3)O_(4)@NiCoLDH_(NSs)array served as supercapacitor electrode exhibits excellent electrochemical properties,such as high specific capacitance of 1708 F g^(-1)(850 C g^(-1))at a current density of 1 A g^(-1),good rate capability,and excellent cycling stability.Further,the asymmetric supercapacitor assembled by Co_(3)O_(4)@NiCoLDH_(NSs)and activated carbon,also displays superior electrochemical perfo rmance with high energy density and power density.Remarkably,the strategy of constructing core-shell structure based on MOF templates could be extended to other electrochemical fields.
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