3-叠氮基-4-酰氯肟基呋咱的合成及其热稳定性

摘要

A novel compound, 3-azido-4-carboxchloridoximefurazan(3) , in overall yield of 67% was synthesized by diazotization and azidation from 3-amino-4-amidoximinofurazan. The structure was characterized by 1H NMR, 13C NMR, 15N NMR, IR, MS and elemental analysis. The results showed that 3 exhibited good thermal stability by DSC.%以3-氨基-4-酰氨肟基呋咱为原料,经重氮化和叠氮化反应合成了新化合物3-叠氮基-4-酰氯肟基呋咱(3),总收率67％.其结构经1H NMR,13C NMR,15N NMR,IR及元素分析表征.热失重法研究结果表明,3具有良好的热稳定性.