新型非对称1,1′-双取代咪唑二茂铁的合成

摘要

以二茂铁为原料,通过Friedel-Crafts烷基化反应、Vilsmeier-Haack反应等合成了12个新型1-取代咪唑二茂铁与非对称1,1′-双取代咪唑二茂铁,其结构经1H NMR,IR和ESI-MS表征.%Twelve novel imidazole ferrocenes and asymmetrical 1 ,1'-bisimidazole ferrocenes were synthesized from ferrocene by Friedel - Crafts alleviation reaction, Vilsmeier - Haack reaction and so on. The structures were characterized by 1H NMR, IR and ESI-MS.