Synthesis and Crystal Structure of a New Ternary Mixed Ligand Complex Cu(ampym)(bapa)Cl(ClO4) (ampym = 2-Aminopyrimidine, bapa = Bi(3-aminopropyl)amine)

摘要

cqvip:The title complex [Cu(ampym)(bapa)Cl](ClO4) (C10H22Cl2CuN6O4) was synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The crystal crystalli- zes in the orthorhombic system, space group Pna21 with a = 11.9904(12), b = 15.9796(16), c = 8.9143(9) ’, V = 1708.0(3) ·3, Mr = 424.78, Z = 4, F(000) = 876, Dc = 1.652 g/cm3, T = 293 K, μ = 1.619 mm–1 and λ = 0.71073 ’. The structure was refined to R = 0.0240 and wR = 0.0564 for 2905 observed reflections with I > 2σ(I). Flack = 0.039(12).