Synthesis and Crystal Structure of 1,4-Bis(benztriazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene

摘要

The title compound 1,4-bis(benztriazol-1-ylmethyl)-2,4,5,6-trimethylbenzene crystallizes in the monoclinic system, space group Pbca with a = 9.842(5), b = 9.455(5), c = 22.165(12)(A), V = 2062.6(18) (A)3, Dc = 1.277 g/cm3, Z = 4, C24H24N6, Mr = 396.49, μ(MoKa) = 0.079 mm-1 and F(000) = 840. The structure was refined to R = 0.0662 and Wr = 0.1891 for 1163 observed reflections (I > 2((I)). The title molecule has trans-conformation about the central phenyl ring. The zigzag-like molecules are connected by face-to-faceπ…π stacking to form an infinite 2D layer.