Structure Characterization and Dephosphorization Effect Analysis of Oyster Shell-silica Micropowder Waste Water Dephosphorization Materials

摘要

In this work,the effects of pH value of waste water and initial concentration of phosphorus on dephosphorization materials were investigated.The materials were prepared by shaping,sintering and hydrothermal reshaping oyster shell and silica micro-powder.Different concentrations of phosphorus-contained waste water were simulated with potassium dihydrogen phosphate solution,the effect of dephosphorization was tested with phosphomolybdenum blue spectrophotometer method,and the crystal phase and microstructure of materials were characterized by XRD and SEM methods.It was indicated that dephosphorization was completed in 6 h when the initial phosphorus concentration in waste water was lower than 15 mg/L,and the dephosphorization time prolonged as the increase of phosphorus concentration.It was observed that the pH value of waste water influenced dephosphorization significantly,and neutral subalkalic environment favored dephosphorization.When the pH value was 11,the efficiency of dephosphozation was the greatest.For waste water with an initial concentration of 20 mg/L,the dephosphozation rate is close to 100% in 8 h.