Synthesis, Crystal Structure and Luminescent Properties of the Indium(Ⅲ) Complex Based on 2,6-Bis(1-phenylbenzimidazol-2-yl)pyridine

摘要

The complex [In(bpbp)Cl3]·H2O, where bpbp is 2,6-bis(1-phenylbenzimidazol- 2-yl)-pyridine (bpbp), was synthesized and characterized by X-ray single-crystal structure analysis. For the complex: C31H21Cl3InN5·H2O, Mr = 702.71, monoclinic, space group, P21/n, a = 9.3918(10), b = 21.024(2), c = 14.5323(15), β = 96.938(2)°, V = 2848.4(5)3, Z = 4, Dc = 1.639 g/cm3, λ = 0.71073, μ(MoKα) = 1.147 mm-1, F(000) = 1408, S = 1.00, R = 0.0430 and wR = 0.1438 for 4620 observed reflections with Ⅰ > 2σ(Ⅰ). It is a neutral complex. The In(Ⅲ) ion adopts a distorted trigonal bipyramidal geometry coordinated by three nitrogen atoms of the ligand and three chlorine atoms. The complex emits blue luminescence with emission peaks at 430 nm in the solid state.