SWELLING AND WETTABILITY OF LIGHT-CURED METHACRYLATE-BASED DENTAL RESINS PREPARED FROM CHOLIC ACID

摘要

2′-methacryloxy-3α, 7α, 12α - trimethacryloyl cholic acid ethyl ester (CAGE4MA) has been prepared from cholic acid. Photo-polymeric resins were prepared from CAGE4MA. 2,2-bis4-(2-hydroxy-3-methacrylyloxypropoxy)phenylpropane (bis-GMA) was used for comparison, triethyleneglycol dimethacrylate (TEGDMA) was used as diluent. The polymerization was initiated by camphoroquinone (CQ)N, N-dimethylaminoethyl methacrylate (DMAEMA) system. The conversion of CAGE4MA was 39% when the reaction time is 60s, which is lower than bis-GMA and TEGDMA. The swelling value of CAGE4MA resin was 0.41% in distilled water, which is much lower than those of bis-GMA resin (2.04%) and TEGDMA resin (4.77%) under the same conditions. Copolymers from CAGE4MA and TEGDMA have been prepared. With the increase of TEGDMA in mixture, the degree of conversion of CAGE4MA and swelling value increased. The swelling values of photocured resins in 0.1molL HCl were also measured.