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Synthesis and Performance of Titanium Organic Gel Doped with Rare Earth

         

摘要

White nano-titanium organic compound-gel with steady performance was synthesized by sol-gel method. This gel has good absorbency to ultraviolet rays. Specially, the absorption wavelength of the organic gel shifted from 250.9 to 254.3 nm(doped with La) and 257.8 nm(doped with Ce), respectively and the absorption peak broadened. The broadening extent has direct ratio with the doping content. It is indicated that when the thickness of the organic gel coat is 60 μm, 98.8% ultraviolet with radiation intensity of 17.2 μW·cm -2 is blocked off. The TEM test shows that the diameter of the titanium organic gel doped with lanthanum is about 5 nm and the granules are uniform. It is indicated that by X-ray this organic substance is amorphous state and it will form nano-TiO2 with anatase structure calcined at 450 ℃.

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