Eu(III) complexes with chosen Keggin polyoxomatalates, POM, containing organic counter cations (tetrabutylammonium, tetrabutylphosphonium, triphenylethylphosphonium), were synthesized, and their photophysical properties were studied. The synthesized complexes had the general formula of XnH5-n[EuSiW11O39], formulated based on the results of elemental and thermogravimetric analysis and FTIR spectroscopy. The photophysical properties of the obtained compounds were investigated using photoluminescence and electro- chemiluminescence, ECL, methods in solutions and solids. The most intense luminescence of Eu(III) was observed for the complexes with tetrabutylammonium cations. After the addition of phenanthroline to the XnH5-n[EuSiW11O39] solutions, a large increase in the Eu(III) lumi- nescence intensity and a lengthening of its luminescence lifetime were observed as a result of the formation of ternary complexes. Attempts to apply ECL as a method of light emission by generating species capable of forming excited states in Ln/POMs, i.e., Tb(III) and Eu(III) in the Na9EuW10O36 and Na9TbW10O36 complexes, were made. The influence of the POM complexes on the ECL was also tested using the Tb/EDDHA (EDDA=ethylenediamine di(o-hydroxyphenylacetic acid)) complex, which is effective in generating ECL.
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