Reductive Coupling of Alkyl Selenocyanates to Diselenides Utilizing Environmentally Benign TiCl4-NEt3 Reagent

摘要

@@ The reduction of TiCl4 to low valent titanium (LVT) species and the synthetic utility of such species are welldocumented chemistry of wide interest. [1] Generally, reducing agents such as Mg, Zn, Li, Sm, Pb-Te and LiAlH4are used for reduction of TiCl4.[2]