With the rapid development of polymer science and catalysis technology,it has become more and more important to understand the microstructures of polymer and catalyst. In the paper,the recent applications of ESR and NMR in studyingmetallocene catalyst and polyolefin are reviewed. The results suggest that the ESR and NMR techniques useful research tools in studying the microstructure of polymers and catalysts.%随着高分子科学和催化技术的发展,了解聚合物和催化剂的微结构信息尤为重要. 主要介绍了ESR和NMR在茂金属催化剂和聚烯烃领域中的最新应用,研究成果表明ESR和NMR是研究聚合物和催化剂微观信息的有效工具.
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