The μ-oxygen-bis[tri(p-fluorobenzyl)tin] was synthesized. The structure were characterized by elementary analysis, IR and 1H NMR and the crystal structure were determined by X-ray single crystal diffraction. The crystal of the title compound belongs to rhombohedral with space group R, α=1.3464(4), b=1.3464(4), c=1.7729(7)nm, α=90°，β=90°, γ=120°, Z=3, V=2.7832(15)nm3, Dc=1.625g·cm-3,μ(Mo Kα)=1.408mm-1, S=1.088, F(000)=1350, R1=0.0275, ωR2=0.0659. In compound,the tin atom has a distorted tetrahedral coordination configuration. CCDC: 257079.
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