N,N'-双(4-甲基-2-苯并噻唑基)-2,6-吡啶二酰胺钴(Ⅱ) 配合物的合成和晶体结构

摘要

Treatment of deprotonated N,N'-bis(4-methyl-2-benzothiazolyl)-2, 6-pyridicarboxamide (L2-) with CoCl2·been carried out for the complex, crystal system: Monoclinic, space group: P21/c, a=1.444(1) nm, b=1.969(1) nm,c=2.448(1) nm,β=118.02(1)°, V=6.143 0(15) nm3, Z=4. In this complex, the central Co(Ⅱ) atom is in an octahe-dron environment, with four deprotonated amide-N atoms in the equatorial plane and two pyridine-N atoms in theaxial positions. CCDC: 252558.