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具有自旋涨落性质的单一手性三核镍(Ⅱ)配合物

     

摘要

[Ni3O(TBPLA)(H2O)](ClO4)4(H2O)6 [TBPLA=(S)-1,1',1"-2,4,6-trimethylbenzene-1,3,5-triyl)-tris(methylene)-tris-(pyrrolidine-2-carboxylate)] was found to possibly display multiferroic property (the coexistence of ferroelectricity and ferromagnetism). The magnetic property of this compound was studied and no magnetic hysteresis loop was found probably due to an intrinsic fluctuation for the magnetic exchange energy.

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