采用水热法合成了一个配合物[Co(AIP)(HAIP)2]·(OH)2(HAIP=2-(9-anthryl)-1H-imidazo[4,5-f][1,10] phenanthroline)1,并对其进行了元素分析、红外光谱、热重表征和X射线单晶衍射测定.配合物1属于单斜晶系,空间群为C2/c,晶胞参数为:a=1.152 9(2),b=3.673 6(7),c=1.584 1(3) nm,α=107.73(3).,V=6.382(2) nm3,Z=4(291(2)K).在晶体中,中心离子Co(Ⅲ)分别与来自于2个不同的HAIP配体和1个AIP配体上的6个氮原子形成六配位的变形八面体构型.%One compound [Co(AIP)(HAIP)2]·(OH)2(LH=2-(9-anthryl)-1H-imidazo[4,5-f][1,10] phenanthroline) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,TG and single-crystal X-ray diffraction.The compound 1 crystallizes in the monoclinic system,space group C2/c,with a=1.152 9(2),b=3.673 6(7),c=1.584 1(3) nm,β=107.73(3),V=6.382(2) nm3,Z=4 (at 291(2) K).In the crystal structure,the Co(Ⅲ) ion is six match coordination with six nitrogen atoms which from two different HAIP ligands and one AIP ligand,assuming a slightly distorted octahedral.
展开▼
