The study of methanol aromatization on transition metal modified ZSM-5 catalyst

摘要

In this article,transition metals ofCu,La and Zn were used as adjuvant to prepare modified HZSM-5 by impregnation method.The catalysts were characterized by XRD,BET,NH3-TPD and Py-IR to reveal the microstructure and acid property.The catalysis performances of methanol aromatization of catalysts were investigated in a fixed-bed reactor.The results show that the strength and distribution of acid center of these catalysts are significantly influenced by the species of transition metal.There are more mediate strong Lewis acid center in Zn modified HZSM-5 catalyst and therefore exhibits higher selectivity to aromatic,benzene,toluene and xylenes in the MTA reaction.