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Kinetics of Photocatalytic Degradation of Gaseous Organic Compounds on Modified TiO2/AC Composite Photocatalyst

机译:改性TiO2 / AC复合光催化剂上气态有机物光催化降解的动力学

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摘要

This study is focused on the kinetic characteristics of photocatalytic degradation of gaseous organic compounds on modified titanium dioxide/activated carbon composite photocatalyst (MTA). The MTA, which co-doping with iron (Fe) and nitrogen (N), was synthesized by a sol-gel method, and its photocatalytic performance was investigated under different reaction conditions. The experimental data obtained were tested by the zero, first and second order kinetic model, and the factors affecting the kinetic model were analyzed. It was clearly demonstrated that the experimental data of toluene and acetone on MTA fit quite well with second order kinetic model equation, but the experimental data of formaldehyde fits well with zero order kinetic model equation.
机译:重点研究了改性二氧化钛/活性炭复合光催化剂(MTA)对气态有机化合物光催化降解的动力学特性。通过溶胶-凝胶法合成了铁(Fe)和氮(N)共掺杂的MTA,并研究了其在不同反应条件下的光催化性能。通过零阶,一阶和二阶动力学模型测试获得的实验数据,并分析影响动力学模型的因素。清楚地表明,甲苯和丙酮在MTA上的实验数据与二阶动力学模型方程拟合得很好,而甲醛的实验数据与零阶动力学模型方程拟合得很好。

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